4 years ago

Transition-Metal-Free Reaction of Aryltrimethylammonium Iodides with Arylzinc Reagents

Transition-Metal-Free Reaction of Aryltrimethylammonium Iodides with Arylzinc Reagents
Wei-Can Dai, Zhong-Xia Wang
The reaction of aryltrimethylammonium salts with arylzinc chlorides to form biaryls was previously performed using transition-metal catalysts. Now, the transformation can be achieved via transition-metal-free aromatic substitution under mild conditions. A wide substrate scope and good functional-group tolerance were observed. The reaction could be performed on a gram scale, thus showing the practicality of this transformation. More information can be found in the Communication by Wei-Can Dai and Zhong-Xia Wang.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/asia.201701464

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