Anionic polymerization of ethyl acrylate initiated by tetrabutylammonium azide: direct synthesis of end-clickable polyacrylate

4 years ago

Anionic polymerization of ethyl acrylate initiated by tetrabutylammonium azide: direct synthesis of end-clickable polyacrylate

Tatsuki Kitayama, Yasuhiro Kohsaka, Yuki Kataoka, Takehiro Kitaura, Shoya Ishihara, Shogo Domae

Tetrabutylammonium azide, a weak nucleophile, was found to initiate the living anionic polymerization of ethyl acrylate in the presence of alkylaluminum bisphenoxides as monomer activators to afford clickable azide-end polymers.

Publisher URL: http://feeds.rsc.org/~r/rss/PY/~3/xdQPAO37ytQ/C7PY00560A

DOI: 2017/PY/C7PY00560A

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