Organic Letters
Organic Letters
5 years ago

Hydropyridylation of Olefins by Intramolecular Minisci Reaction

Hydropyridylation of Olefins by Intramolecular Minisci Reaction
Samuele Bordi, Jeremy T. Starr
An unprecedented cheap, mild and easy methodology for an intramolecular Minisci reaction based on a hydrogen atom transfer (HAT) initiated hydrofunctionalization of olefins was developed. The method is suitable for the construction of unusual dihydropyrano-pyridine and 1,2,3,4-tetrahydronaphthiridine structures and, unlike most similar reactions, does not require exclusion of air from the reaction medium.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b00833

DOI: 10.1021/acs.orglett.7b00833

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