Inorganica Chimica Acta
Inorganica Chimica Acta
5 years ago

Influence of metal ions on the selective catalytic oxidation properties of isostructural MOFs

Influence of metal ions on the selective catalytic oxidation properties of isostructural MOFs
Two new metal–organic frameworks (MOFs) [Co(AIA)(3-bpdh), Mn(AIA)(3-bpdh)], featuring 2-dimensional layer network topologies are successfully assembled by the solvent diffusion method as CoII and MnII isostructural MOFs, hereafter, 1Co and 1Mn. Moreover, a series of micro-crystals of these two kinds of MOFs with different morphologies and sizes are also obtained by adjusting the synthesis systems. Interestingly, one MOF exhibits selective catalytic oxidation properties for the degradation of malachite green dye, whereas the other MOF shows corresponding properties for methylene blue. In addition, a detailed possible oxidation catalytic mechanism is proposed. This work highlights that MOFs are functional materials for selective dye degradation and demonstrates that metal ion replacement is an efficient way to regulate MOFs for deserving applications.

Publisher URL: www.sciencedirect.com/science

DOI: S0020169317311222

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.