5 years ago

Fluorine in a C-F Bond as the Key to Cage Formation

Thomas Lectka, Maxwell Gargiulo Holl, Cody Ross Pitts
Cage molecules have long been employed to trap reactive or fleeting species, as their rigid nature allows them to enforce situations that otherwise would not persist. In this minireview, we discuss our use of rigid cage structures to investigate the close noncovalent interactions of fluorine with other functional groups and determine how mutual proximity affects both physical properties and reactivity. Unusual covalent interactions of fluorine are also explored: the cage can close to form the first solution-phase C-F-C fluoronium ion.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201710423

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