Journal of Organic Chemistry
Journal of Organic Chemistry
4 years ago

Bimetallic Cobalt–Rhodium Nanoparticle-Catalyzed Reductive Amination of Aldehydes with Nitroarenes Under Atmospheric Hydrogen

Bimetallic Cobalt–Rhodium Nanoparticle-Catalyzed Reductive Amination of Aldehydes with Nitroarenes Under Atmospheric Hydrogen
Isaac Choi, Young Keun Chung, Supill Chun
A cobalt–rhodium heterobimetallic nanoparticle (Co2Rh2/C)-catalyzed tandem reductive amination of aldehydes with nitroaromatics to sec-amines has been developed. The tandem reaction proceeds without any additives under mild conditions (1 atm H2 and 25 °C). This procedure can be scaled up to the gram scale, and the catalyst can be reused more than six times without loss of activity.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b02019

DOI: 10.1021/acs.joc.7b02019

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