5 years ago

Rh(III)-Catalyzed Direct ortho-Chalcogenation of Phenols and Anilines

Rh(III)-Catalyzed Direct ortho-Chalcogenation of Phenols and Anilines
Boya Feng, Yudong Yang, Shiping Yang
A highly efficient Rh(III)-catalyzed direct C–H chalcogenation of phenols and anilines has been achieved with the assistance of the 2-pyridyl group. The reaction features a broad substrate scope, good functional group tolerance, complete monothiolation selectivity, and easily removable directing group.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b02221

DOI: 10.1021/acs.joc.7b02221

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