Journal of Organic Chemistry
Journal of Organic Chemistry
5 years ago

Synthesis of Chiral Tritylpyrrolidine Derivatives and Their Application to Asymmetric Benzoyloxylation

Synthesis of Chiral Tritylpyrrolidine Derivatives and Their Application to Asymmetric Benzoyloxylation
Mio Shimogaki, Shingo Tsuji, Chihiro Homma, Keiji Maruoka, Taichi Kano, Hiroki Maruyama
An efficient synthesis of novel chiral tritylpyrrolidine derivatives has been developed. Single stereoisomers of various tritylpyrrolidine derivatives can be readily obtained through diastereomer separation by simple silica gel column chromatography. Representative compounds of this class have been shown to be efficient amine organocatalysts for asymmetric benzoyloxylation.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b02562

DOI: 10.1021/acs.joc.7b02562

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