3 years ago

Blue Light Photocatalytic Glycosylation without Electrophilic Additives

Blue Light Photocatalytic Glycosylation without Electrophilic Additives
Peng Wen, David Crich
Photocatalytic formation of glycosidic bonds employing stable and readily accessible O-glycosyl derivatives of 2,2,6,6-tetramethylpiperidin-1-ol is presented that employs an iridium-based photocatalyst and blue LEDs. The reaction proceeds at room temperature and in the absence of additives other than 4 Å molecular sieves. Stereoselectivities are modest but nevertheless dependent on the anomeric configuration of the donor, suggesting a substantial degree of concerted character.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b00932

DOI: 10.1021/acs.orglett.7b00932

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