5 years ago

Synthesis and Structures of Zigzag Shaped [12]Cyclo-p-phenylene Composed of Dinaphthofuran Units and Biphenyl Units

Synthesis and Structures of Zigzag Shaped [12]Cyclo-p-phenylene Composed of Dinaphthofuran Units and Biphenyl Units
Takahiro Sasamori, Kouji Kuramochi, Kentaro Nakanishi, Norihiro Tokitoh, Takaaki Shouda, Kazunori Tsubaki
A [12]Cyclo-p-phenylene 9 composed of dinaphthofuran units and biphenyl units was synthesized through reductive elimination of the corresponding trinuclear complex by applying Yamago’s method. The X-ray crystallographic analyses of 9 revealed that it adopts a zigzag conformation in the solid state. The UV–vis and fluorescence measurements of compound 9 indicated that it also preferentially took a zigzag conformation in the solution state.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01053

DOI: 10.1021/acs.joc.7b01053

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