3 years ago

Gas Purification: Ultrahigh and Selective SO2 Uptake in Inorganic Anion-Pillared Hybrid Porous Materials (Adv. Mater. 28/2017)

Gas Purification: Ultrahigh and Selective SO2 Uptake in Inorganic Anion-Pillared Hybrid Porous Materials (Adv. Mater. 28/2017)
Rajamani Krishna, Qilong Ren, Banglin Chen, Wei Zhou, Hui Wu, Zongbi Bao, Xili Cui, Qiwei Yang, Huabin Xing, Zhiguo Zhang, Lifeng Yang
Selective recognition and dense packing of SO2 clusters is achieved through multiple synergistic host-guest/guest-guest interactions within SiF62- anion-pillared hybrid porous materials in article number 1606929, by Qiwei Yang, Banglin Chen, Huabin Xing, and co-workers. The binding sites of anions and aromatic rings on the pore surface grasp every atom of SO2 via Sδ+⋯Fδ– and Oδ–⋯Hδ+ interactions, while the interactions between SO2 molecules further promote the gas trapping.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/adma.201770205

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