3 years ago

Back Cover: Design, Synthesis, and Chemistry of Bis(σ)borate and Agostic Complexes of Group 7 Metals (Chem. Eur. J. 41/2017)

Back Cover: Design, Synthesis, and Chemistry of Bis(σ)borate and Agostic Complexes of Group 7 Metals (Chem. Eur. J. 41/2017)
Thierry Roisnel, Kriti Pathak, Sundargopal Ghosh, Vincent Dorcet, Jean-François Halet, Rongala Ramalakshmi, Koushik Saha, Suman Gomosta
The lability of the CO ligands of manganese bis(σ)borate complex, [Mn(CO)3(μ-H)2HB(NCSC6H4)NR] (R=NCSC6H4) was studied with different phosphine ligands. Treatment of this Mn-bis(σ)borate complex with PPh3 led to the formation of two manganese bis(σ)borate complexes, [(PPh3)(CO)2Mn(μ-H)2HB(NCSC6H4)NR] and [(PPh3)(CO)2Mn(μ-H)2HBNR(NCSC6H4)] (R=NCSC6H4), as structural isomers having two different arrangements of the bis(benzothiazol-2-yl)amine ligand around the central metal atom. More information can be found in the Full Paper by S. Ghosh et al. on page 9812.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201702439

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