3 years ago

Dinuclear Coordination Compounds Based on a 5-Nitropicolinic Carboxylate Ligand with Single-Molecule Magnet Behavior

Dinuclear Coordination Compounds Based on a 5-Nitropicolinic Carboxylate Ligand with Single-Molecule Magnet Behavior
Antonio Rodríguez-Diéguez, Itziar Oyarzabal, José Manuel Seco, Francisco M. Arrabal-Campos, Ignacio Fernández, Álvaro Raya-Barón
Novel air-stable coordination compounds based on a 5-nitropicolinic carboxylate were synthesized and characterized. Dysprosium-based complex exhibits SMM behavior with frequency dependence of the out-of-phase susceptibility at zero dc field. High-resolution MS (ESI) and diffusion NMR experiments suggest that the dinuclear skeleton of these compounds is robust and maintained in solution.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00388

DOI: 10.1021/acs.inorgchem.7b00388

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