Inorganic Chemistry
Inorganic Chemistry
5 years ago

Optical Spectra and Magnetic Behavior of a Wide Range of Europium(III) Oxo-Compounds: Analysis of the Ligand-Field Effects

Optical Spectra and Magnetic Behavior of a Wide Range of Europium(III) Oxo-Compounds: Analysis of the Ligand-Field Effects
Robert Glaum, Nils Kannengießer, Anna Bronova
High-resolution powder reflectance spectra and temperature-dependent magnetic moments were measured for a series of nine europium(III) oxo-compounds including C-type Eu2O3. The various low-symmetry ligand fields were analyzed within the AOM framework using computer program BonnMag. A surprisingly large second-sphere ligand-field effect was thus discovered.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01287

DOI: 10.1021/acs.inorgchem.7b01287

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