Inorganic Chemistry
Inorganic Chemistry
5 years ago

Highly Efficient Catalytic Route for the Synthesis of Functionalized Silsesquioxanes

Highly Efficient Catalytic Route for the Synthesis of Functionalized Silsesquioxanes
Grzegorz Hreczycho, Joanna Kaźmierczak, Krzysztof Kuciński
The first example of a metal-catalyzed method for the corner-capping reaction has been reported. Our methodology provides an access for the synthesis and functionalization of various polyhedral oligomeric silsesquioxanes (POSS). This scandium(III) triflate catalyzed reaction showed a broad substrate scope and excellent functional group tolerance and afforded the corresponding products in good to excellent yields under extremely mild conditions.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01504

DOI: 10.1021/acs.inorgchem.7b01504

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