3 years ago

Rhodium-Catalyzed Alkenylation of C–H Bonds in Aromatic Amides with Alkynes

Rhodium-Catalyzed Alkenylation of C–H Bonds in Aromatic Amides with Alkynes
Satoko Natsui, Naoto Chatani, Kaname Shibata
The rhodium-catalyzed alkenylation of C–H bonds of aromatic amides with alkynes is reported. A variety of functional groups, including OMe, OAc, Br, Cl, and even NO2, are applicable to this reaction to give the corresponding hydroarylation products. The presence of an 8-aminoquinoline group as the directing group is crucial for the success of the reaction.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b00709

DOI: 10.1021/acs.orglett.7b00709

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