Journal of Organic Chemistry
Journal of Organic Chemistry
5 years ago

Synthesis of Oxatricyclooctanes via Photoinduced Intramolecular Oxa-[4+2] Cycloaddition of Substituted o-Divinylbenzenes

Synthesis of Oxatricyclooctanes via Photoinduced Intramolecular Oxa-[4+2] Cycloaddition of Substituted o-Divinylbenzenes
Dazhi Li, Wujiong Xia, Qiang Liu, Yuan Gao, Chao Yang, Junlei Wang, Guo-Lin Gao
The photolysis of substituted o-divinylbenzenes promotes a one-step and metal-free conversion to oxatricycles at room temperature. Irradiation o-divinylbenzenes results in an pericyclic reaction to form cyclic o-quinodiemthane intermediates, which subsequently undergo intramolecular oxa-[4+2] cycloaddition to form oxacyclic derivatives.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01055

DOI: 10.1021/acs.joc.7b01055

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