5 years ago

Transition Metal Functionalization of P4 Using a Diarylgermylene Anchor

Transition Metal Functionalization of P4 Using a Diarylgermylene Anchor
Philip P. Power, Charles L. B. Macdonald, Zachary D. Brown, Cameron M. E. Graham, Paul J. Ragogna
Once elemental phosphorus has been activated by a low-valent diaryl germylene, the addition of Lewis acidic transition metal complexes leads to the formation of Lewis acid−base compounds, stemming from P4 as the electron pair donor. This process is both high yielding and highly selective, which is desirable for the manipulation of small molecules.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01138

DOI: 10.1021/acs.inorgchem.7b01138

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