Inorganic Chemistry
Inorganic Chemistry
5 years ago

Several [Gd-M] Heterometal–Organic Frameworks with [Gdn] as Nodes: Tunable Structures and Magnetocaloric Effect

Several [Gd-M] Heterometal–Organic Frameworks with [Gdn] as Nodes: Tunable Structures and Magnetocaloric Effect
Peng-Fei Shi, Bin Zhao, Chu-Ming Wang, Chun-Shuai Cao
Structures and MCE of seven MOFs characterized [Gdn] as nodes are tuned elaborately. The [Gdn] node is realized from mononuclear [Gd] to binuclear paddle-wheel [Gd2], tetranuclear tetrahedral [Gd4], and pentanuclear trigonal bipyramidal [Gd5]. Meanwhile, the −ΔSm changes from 19.4 to 46.0 J·kg−1·K−1. The results reveal the effect of magnetic density on MCE plays a dominant role for Gd3+-based compounds.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01209

DOI: 10.1021/acs.inorgchem.7b01209

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