Inorganic Chemistry
Inorganic Chemistry
5 years ago

Tailor-Made Luminescent Polymers through Unusual Metallophilic Interaction Arrays Au···Au···Ag···Ag

Tailor-Made Luminescent Polymers through Unusual Metallophilic Interaction Arrays Au···Au···Ag···Ag
M. Concepción Gimeno, David Pascual, José M. López-de-Luzuriaga, M. Elena Olmos, Miguel Monge, María Gil-Moles
A novel and efficient strategy for the synthesis of luminescent polymers bearing metallophilic interactions with unprecedented + + − − + + − − charge sequences has been designed. For this end suitable basic gold units such as [AuR2]−, bearing perhalophenyl derivatives, and the dinuclear acid silver terpyridine compound, [Ag(OTf)(terpy)]2, have been chosen, which combination originates the polymeric derivatives [(AuR2)2Ag2(terpy)2]n.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01342

DOI: 10.1021/acs.inorgchem.7b01342

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