Inorganic Chemistry
Inorganic Chemistry
5 years ago

Syntheses, Structures, and Comparisons of Heterometallic Uranyl Iodobenzoates with Monovalent Cations

Syntheses, Structures, and Comparisons of Heterometallic Uranyl Iodobenzoates with Monovalent Cations
Korey P. Carter, Anton V. Savchenkov, Mark Kalaj, Christopher L. Cahill, Mikaela M. Pyrch
Six new heterometallic compounds containing the UO22+ cation, o-, m-, and p-iodobenzoic acid ligands, and Tl+, Rb+, and Cs+ cations which adopt the role of both charge balancing cation and secondary metal center have been synthesized and their structural, supramolecular, and luminescent properties have been explored. Additionally, these compounds have been probed via Voronoi−Dirichlet tessellation and Hirshfeld surface analysis as part of an effort to develop metrics for determining the coordination number of secondary metal cations in similar systems.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01208

DOI: 10.1021/acs.inorgchem.7b01208

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.