3 years ago

Cobalt-catalysed reductive C-H alkylation of indoles using carboxylic acids and molecular hydrogen

Cobalt-catalysed reductive C-H alkylation of indoles using carboxylic acids and molecular hydrogen
Rosa Adam, Jose R. Cabrero-Antonino, Matthias Beller, Kathrin Junge
The first direct CH-alkylation of indoles using carboxylic acids and hydrogen is presented. A non-noble metal based catalytic system, [Co(acac)3/Triphos/Al(OTf)3], efficiently catalyses the alkylation of a variety of indoles with a wide range of carboxylic acids.

Publisher URL: http://feeds.rsc.org/~r/rss/SC/~3/dGoIZE5RZF4/C7SC02117H

DOI: 2017/SC/C7SC02117H

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