Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Cover Picture: Silyl Chalconium Ions: Synthesis, Structure and Application in Hydrodefluorination Reactions (Chem. Eur. J. 42/2017)

Cover Picture: Silyl Chalconium Ions: Synthesis, Structure and Application in Hydrodefluorination Reactions (Chem. Eur. J. 42/2017)
Thorben Sieling, Natalie Kordts, Marc Schmidtmann, Saskia Rathjen, Sandra Künzler, Henning Großekappenberg, Thomas Müller
Silylated chalconium ions based on peri-naphthalene and acenaphthene scaffolds are synthesized and introduced as versatile amphiphilic reagents. The investigation of their spectroscopic, structural and bonding properties revealed that their silyl Lewis acidity is controlled by the nature of the chalcogen donor and by the carbon backbone. This opens the perspective for an effective fine tuning and control of their reactivity. Their use as amphiphilic CATalyst was exemplarily demonstrated in hydrodefluorination reactions. More information can be found in the Full Paper by T. Müller et al. on page 10068.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201702049

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.