5 years ago

Trifluoromethyl- and Fluoroalkylselenolations of Alkynyl Copper(I) Compounds

Trifluoromethyl- and Fluoroalkylselenolations of Alkynyl Copper(I) Compounds
Thierry Billard, Anis Tlili, Clément Ghiazza
The successful perfluoroalkylselenolation of alkynyl copper(I) compounds is described herein. The reaction occurs under oxidant free conditions at room temperature. This convenient one-pot procedure is based on the in situ generation of trifluoromethylselenyl chlorides. The developed system shows high functional group tolerance and also promotes the employment of fluoroalkyl derivatives. The successful fluoroalkylselenolation of alkynyl copper(I) is described herein. The system shows high functional group tolerance and the applicability of the procedure is extended to various fluoroalkyl derivatives. This convenient one-pot procedure occurs under oxidant-free conditions at room temperature.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201702028

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