Reactivity of N-heterocyclic carbene-pyridine palladacyclopentadiene complexes toward halogen addition. The unpredictable course of the reaction

5 years ago

Reactivity of N-heterocyclic carbene-pyridine palladacyclopentadiene complexes toward halogen addition. The unpredictable course of the reaction

Claudio Santo, Fabiano Visentin, Thomas Scattolin, Luciano Canovese, Nicola Demitri

Novel Pd(II) complexes characterized by a ten term coordinative ring have been obtained when palladacyclopentadienyl complexes were reacted with I₂. The rearrangement kinetics, and a computational study suggesting a plausible mechanism are reported.

Publisher URL: http://feeds.rsc.org/~r/rss/DT/~3/nVh91qG18SM/C7DT02162C

DOI: 2017/DT/C7DT02162C

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