3 years ago

Construction of Di(hetero)arylmethanes Through Pd‐Catalyzed Direct Dehydroxylative Cross‐Coupling Benzylic Alcohols and Aryl Boronic Acids Mediated by Sulfuryl Fluoride (SO2F2)

Chuang Zhao, Gao-Feng Zha, Wan-Yin Fang, K. P. Rakesh, Hua-Li Qin

Abstract

A practical Pd‐catalyzed direct dehydroxylative coupling of (hetero)benzylic alcohols with (hetero)arylboronic acids for the constructions of di(hetero)arylmethane derivatives under SO2F2 was described. This new method provided a strategically distinct approach to di(hetero)arylmethane derivatives from readily available and abundant benzylic alcohols under mild condition.

Publisher URL: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.201801888

DOI: 10.1002/ejoc.201801888

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