Chemical Communications
Chemical Communications
4 years ago

Cooperative carbon monoxide to formyl reduction at a trifunctional PBB frustrated Lewis pair

Cooperative carbon monoxide to formyl reduction at a trifunctional PBB frustrated Lewis pair
Yasuharu Hasegawa, Senwang Zhang, Gerald Kehr, Long Wang, Constantin G. Daniliuc, Gerhard Erker
Twofold hydroboration of the bulky Mes*P(vinyl)2 phosphane with Piers' borane [HB(C6F5)2] followed by C6F5/H exchange with 9-BBN generated a reactive P/B/BH FLP structure that cleanly reduced carbon-monoxide at the trifunctional frustrated Lewis pair framework to the [B]-formyl stage.

Publisher URL: http://feeds.rsc.org/~r/rss/CC/~3/_b8lh0EK3XA/C7CC02214J

DOI: 2017/CC/C7CC02214J

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