3 years ago

Cationization of cellulose/polyamide on UV protection, bio-activity, and electro-conductivity of graphene oxide-treated fabric

Cationization of cellulose/polyamide on UV protection, bio-activity, and electro-conductivity of graphene oxide-treated fabric
Majid Montazer, Mahfam Hasani
In this work, cationized cotton/nylon fabric was treated with reduced graphene oxide (rGO) to produce highly conductive fabric. The fabric was cationized with 3-chloro-2-hydroxy propyl trimethyl ammonium chloride to attract more anionic GO. The fabric was then treated with GO followed by reduction with sodium dithionite. The results of energy-dispersive X-ray spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy indicated entire coverage of the fabric surface with rGO. The color of fabrics changed to gray-black and the electrical resistance decreased to 0.6 × 103 Ω sq−1. The washing fastness was measured according to ISO 105-CO5 for color change and also electrical resistance of the samples demonstrated well stability of rGO on the fabric surface. The antibacterial activities of the treated fabrics improved against Gram-negative bacteria including Escherichia coli (84.8%) and Pseudomonas aeruginosa (96.4%) and also Gram-positive bacteria consisting Staphylococcus aureus (100%) and Enterococcus faecalis (98.4%). Further, the treated fabrics indicated an excellent UV reflectance of 100%. Finally heating of the cationized rGO fabric at 220 °C displayed a lower electrical resistance of 0.5 × 103 Ω sq−1. The thermogravimetric analysis showed that heating has a slight effect on the dimensional thermal stability of the treated fabric as shrunk 2.43%. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45493.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/app.45493

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