5 years ago

Synthesis and activation potential of an open shell diphosphine

Synthesis and activation potential of an open shell diphosphine
Jutta Kosters, Alexander Villinger, Stephan Ludwig, Kai Helmdach, Dirk Hollmann, Wolfram W. Seidel
A cationic bisphosphine assembled by a modular synthetic concept and carrying a paramagnetic S = 1/2 tungsten centre in the backbone shows an unusual spontaneous splitting of nitric oxide assisted by H atom transfer steps.

Publisher URL: http://feeds.rsc.org/~r/rss/CC/~3/sXvGsChlQzE/C7CC02114C

DOI: 2017/CC/C7CC02114C

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