5 years ago

Catalytic, Reversible Arylation of Phosphines and Sulfides

Catalytic, Reversible Arylation of Phosphines and Sulfides
Rylan J. Lundgren
A fair exchange: Morandi and co-workers have reported a process that enables the exchange of aryl groups on sulfur or phosphorus. Building on established aryl-transfer reactions, this Pd-catalyzed metathesis can be used to diversify thioanisoles and generate cyclic phosphines.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201706328

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