Inorganic Chemistry
Inorganic Chemistry
4 years ago

Tetrahedral Copper(II) Complexes with a Labile Coordination Site Supported by a Tris-tetramethylguanidinato Ligand

Tetrahedral Copper(II) Complexes with a Labile Coordination Site Supported by a Tris-tetramethylguanidinato Ligand
Nobutaka Fujieda, Tsukasa Abe, Sayantan Paria, Kaori Asano, Hideki Sugimoto, Dieter Faltermeier, Yuma Morimoto, Takeyuki Suzuki, Shinobu Itoh, Peter Comba, Marion Kerscher, Ikuma Shimizu
Copper(II) complexes with a trigonal pyramidal (“tetrahedral”) geometry with C3v symmetry containing a labile coordination site have been prepared by using a new tridentate N3 ligand (TMG3tach) consisting of cis,cis-1,3,5-triaminocyclohexane (tach) and three N,N,N′N′-tetramethylguanidino (TMG) groups.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01154

DOI: 10.1021/acs.inorgchem.7b01154

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