Polymer
Polymer
5 years ago

Design of novel photobase generators upon violet LEDs and use in photopolymerization reactions

Design of novel photobase generators upon violet LEDs and use in photopolymerization reactions
Two new near-UV and visible-light-sensitive photobase generators (PBGs) are synthesized and investigated. They are built on a near-UV and visible light sensitive (E)-3-(2,2′-bithiophen-5-yl)-2-cyanoacrylic acid chromophore and a latent strong base such as 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD). Upon irradiation, decarboxylation occurs and the base is released. The anionic curing of epoxy/thiol as well as thiol/divinylsulfone formulations in the presence of these PBGs under LEDs at 385 and 405 nm is studied. More than 60% of conversion of the thiol and epoxy functions is achieved upon LED@385 nm without any post baking.

Publisher URL: www.sciencedirect.com/science

DOI: S0032386117307437

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