Journal of the American Chemical Society
Journal of the American Chemical Society
5 years ago

Tuning the Stability of Pd(IV) Intermediates Using a Redox Non-innocent Ligand Combined with an Organolanthanide Fragment

Tuning the Stability of Pd(IV) Intermediates Using a Redox Non-innocent Ligand Combined with an Organolanthanide Fragment
Violaine Goudy, Grégory Nocton, Carine Clavaguéra, Marie Cordier, Arnaud Jaoul
The unique combination of a divalent organolanthanide fragment, Cp*2Yb, with bipyrimidine (bipym) and a palladium bis-alkyl fragment, PdMe2, allows the rapid formation and stabilization of a PdIV tris-alkyl moiety after oxidative addition with MeI. The crucial role of the organolanthanide fragment is demonstrated by the substitution of bipym by the 4,5,9,10-tetraazaphenanthrene ligand, which drastically modifies the electronic structure and tunes the stability of the PdIV species.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b05634

DOI: 10.1021/jacs.7b05634

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