Journal of Organic Chemistry
Journal of Organic Chemistry
5 years ago

Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents
Mohamed Elsherbini, Thomas Wirth, Jihan Qurban
Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01571

DOI: 10.1021/acs.joc.7b01571

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