Position Assignment and Oxidation State Recognition of Fe and Co Centers in Heterometallic Mixed-Valent Molecular Precursors for the Low-Temperature Preparation of Target Spinel Oxide Materials

5 years ago

Position Assignment and Oxidation State Recognition of Fe and Co Centers in Heterometallic Mixed-Valent Molecular Precursors for the Low-Temperature Preparation of Target Spinel Oxide Materials

Rodolphe Clérac, Andrey Yu. Rogachev, Matthew C. Barry, Xiaoping Wang, Alexander S. Filatov, Zheng Wei, Craig M. Lieberman, Evgeny V. Dikarev, Jun-Liang Liu, Yu-Sheng Chen

Assignment of Fe and Co positions/oxidation states in the molecules of mixed-valent heterometallic diketonate precursors derived from X-ray structural investigation was unambiguously confirmed by a number of complementary techniques.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01032

DOI: 10.1021/acs.inorgchem.7b01032

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