Crystal Growth & Design
Crystal Growth & Design
5 years ago

δ-Polymorph of Manganese Phosphate

δ-Polymorph of Manganese Phosphate
Gregory Neher, Tina T. Salguero
Manganese phosphate readily crystallizes in a fourth polymorphic modification, δ-Mn3(PO4)2. Its structure features a three-dimensional framework of [MnO5] edge-shared with [PO4] resulting in sub-nanometer channels. The high thermal stability of δ-Mn3(PO4)2 and its relationships with β′-Mn3(PO4)2 and LiMnPO4 suggest that it is a common intermediate in manganese-phosphate chemistry.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00816

DOI: 10.1021/acs.cgd.7b00816

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