Inorganic Chemistry
Inorganic Chemistry
4 years ago

A Rare Water and Hydroxyl-Extended One-Dimensional Dysprosium(III) Chain and Its Magnetic Dilution Effect

A Rare Water and Hydroxyl-Extended One-Dimensional Dysprosium(III) Chain and Its Magnetic Dilution Effect
Yi-Quan Zhang, Shan Zhang, En-Cui Yang, Xiao-Jun Zhao, Pu Zhao, Yan Li, Rui Li
A novel water and hydroxyl-extended one-dimensional dysprosium(III) chain was hydrothermally generated, exhibiting effective spin-reversal energy barrier of 88.7 K and favorable intrachain ferromagnetic coupling. The high effective energy barrier of the dysprosium(III) chain is resulting from the collaborate contributions of the intrachain ferromagnetic coupling and the Ising-like anisotropy of the Dy(III) ion, in which the latter is more predominant.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01058

DOI: 10.1021/acs.inorgchem.7b01058

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