Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids

Coordination Behavior of [Cp′′2Zr(η1:1-P4)] towards Different Lewis Acids
Eugenia V. Peresypkina, Maria Eckhardt, Manfred Zabel, Gábor Balázs, Miriam Eberl, Manfred Scheer, Michael Bodensteiner, Ulf Vogel, Andreas E. Seitz
A detailed method for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordination modes and multiple coordination numbers of the tetraphosphabicyclo[1.1.0]butane framework were synthesized. All products, as well as the starting materials, were comprehensively characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray structural analysis. Complex coordination: A detailed procedure for the preparation of [Cp′′2Zr(η1:1-P4)] (1) is presented and the coordination behavior of this complex towards Lewis acidic transition metal fragments of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was comprehensively investigated by computational and experimental studies.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201701380

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.