Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Biphasic Liquid Crystal and the Simultaneous Measurement of Isotropic and Anisotropic Parameters by Spatially Resolved NMR Spectroscopy

Biphasic Liquid Crystal and the Simultaneous Measurement of Isotropic and Anisotropic Parameters by Spatially Resolved NMR Spectroscopy
Martin R. M. Koos, Michael Reggelin, Burkhard Luy, Svenja Wesp, Malin Reller
A moderately concentrated solution of a helically chiral polyisonitrile forms a stable two-phase system in CDCl3 with the dense phase being close to isotropic and the less dense layer forming a completely anisotropic lyotropic liquid crystalline phase. This enables the enantiodifferentiating measurement of isotropic and anisotropic NMR parameters from a single sample by novel spatially resolved NMR methods. More information can be found in the Full Paper by M. Reggelin, B. Luy et al. (DOI: 10.1002/chem.201702126).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201703362

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