3 years ago

Synthesis and Characterization of a Series of Bis-homoleptic Cycloruthenates with Terdentate Ligands as a Family of Panchromatic Dyes

Synthesis and Characterization of a Series of Bis-homoleptic Cycloruthenates with Terdentate Ligands as a Family of Panchromatic Dyes
JinFeng Liao, Giuseppe Calogero, Louise Male, Alessandro Sinopoli, Etienne Baranoff, Thomas W. Rees, Basile F.E. Curchod
An effective synthesis of homoleptic bis-cyclometalated ruthenium complexes Ru(N^N^C)2 is reported. These complexes are panchromatic dyes absorbing up to 900 nm. The effect of the electron-withdrawing susbtituents –COOEt and –CF3 on the UV−visible absorption and redox properties is discussed.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01412

DOI: 10.1021/acs.inorgchem.7b01412

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