Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(I)

5 years ago

Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(I)

Stephanie C. Kosnik, Charles L. B. Macdonald, Jeremy M. Rawson, Maxemilian C. Nascimento

We report the oxidative transfer of the phosphorus(I) centre in [P^Idppe][Br] to tetrathiocin and disulfide ligands. Characterization of the resulting bis(trithio)phosphines and mechanistic insight into the formation of these products is provided.

Publisher URL: http://feeds.rsc.org/~r/rss/DT/~3/8QfZ4U13DIs/C7DT01345K

DOI: 2017/DT/C7DT01345K

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