5 years ago

Monodisperse Fiber-like Micelles of Controlled Length and Composition with an Oligo(p-phenylenevinylene) Core via “Living” Crystallization-Driven Self-Assembly

Monodisperse Fiber-like Micelles of Controlled Length and Composition with an Oligo(p-phenylenevinylene) Core via “Living” Crystallization-Driven Self-Assembly
Mitchell A. Winnik, Yinan Cui, Ian Manners, Xian Yang, Xiaoyu Huang, Daliao Tao, Chun Feng
We report the preparation of a series of fiber-like micelles of narrow length distribution with an oligo(p-phenylenevinylene) (OPV)-core and a poly(N-isopropylacrylamide) (PNIPAM) corona via two different crystallization-driven self-assembly (CDSA) strategies. The average length Ln of these micelles can be varied up to 870 nm by varying the temperature in self-seeding experiments. In addition, seeded growth was employed not only to prepare uniform micelles of controlled length, but also to form fiber-like A-B-A triblock comicelles with an OPV-core.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b02208

DOI: 10.1021/jacs.7b02208

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