Organic Letters
Organic Letters
5 years ago

Total Synthesis of Neomarchantin A: Key Bond Constructions Performed Using Continuous Flow Methods

Total Synthesis of Neomarchantin A: Key Bond Constructions Performed Using Continuous Flow Methods
Amaury Dubart, Michaël Raymond, Émilie Morin, Shawn K. Collins
A synthesis of neomarchantin A has been achieved wherein key bond constructions involving C–O or C–C bond formations were augmented via continuous flow techniques. Of note, the synthesis of neomarchantin A represents the first demonstration of catalytic macrocyclic olefin metathesis as a key step for the synthesis of a macrocyclic bisbibenzyl natural product.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b01127

DOI: 10.1021/acs.orglett.7b01127

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