Advanced Synthesis and Catalysis
Advanced Synthesis and Catalysis
5 years ago

Remote Allylation of Chloromethyl(hetero)arenes with Allyl Pinacolborate via η3-Benzylpalladium Intermediates

Remote Allylation of Chloromethyl(hetero)arenes with Allyl Pinacolborate via η3-Benzylpalladium Intermediates
Ming Bao, Autoren aus Original-ArtikelSheng Zhang, Aziz Ullah, Yoshinori Yamamoto
The inside cover picture, provided by Ming Bao and co-workers, illustrates the unprecedented remote allylation of chloromethyl(hetero)arenes with allyl pinacolborate. The palladium-catalyzed regioselective allylation reaction between chloromethyl(hetero)arenes and allyl pinacolborate proceeded smoothly via η3-benzylpalladium intermediates to provide para-allylated dearomatization products or para-allylated arenes in satisfactory to good yields; the formation of traditional Suzuki coupling products was not observed at all. This novel protocol exhibits good tolerance for various functional groups linked to (hetero)arene rings. Details of this work can be found in the communication on pages xxxx–xxxx (S. Zhang, A. Ullah, Y. Yamamoto, M. Bao, Adv. Synth. Catal. 2017, 359, xxxx–xxxx; DOI: 10.1002/adsc.201700350).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/adsc.201700890

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.