Spin-Canted Antiferromagnetic Ordering in Transition Metal–Organic Frameworks Based on Tetranuclear Clusters with Mixed V- and Y-Shaped Ligands

5 years ago

Spin-Canted Antiferromagnetic Ordering in Transition Metal–Organic Frameworks Based on Tetranuclear Clusters with Mixed V- and Y-Shaped Ligands

Sui-Jun Liu, Chen Cao, Yong-Qiang Chen, Shu-Li Yao, Jing-Lin Chen, He-Rui Wen, Teng-Fei Zheng

Four Co^II, Fe^II, and Ni^II magnetic metal−organic frameworks derived from tetranuclear clusters with some differences have been synthesized by using a mixed-ligand strategy. Complexes 3 and 4 show the coexistence of spin-canting and long-range magnetic ordering.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00682

DOI: 10.1021/acs.cgd.7b00682

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