Inorganic Chemistry
Inorganic Chemistry
5 years ago

Importance of Steric Influences in the Construction of Multicomponent Hybrid Polymetallic Clusters

Importance of Steric Influences in the Construction of Multicomponent Hybrid Polymetallic Clusters
Scott J. Dalgarno, Ross McLellan, Euan K. Brechin, Maria A. Palacios, Sergio Sanz
The assembly of multicomponent calix[4]arene/salicylaldoxime supported polymetallic clusters is modulated by the steric imposition of a series of substituents on the latter ligand type (complementary interactions between ligands shown in figure). In this way, both structural and magnetic properties of the resultant clusters can be modified, while maintaining the expected coordination chemistry of the respective ligands.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01566

DOI: 10.1021/acs.inorgchem.7b01566

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