Inorganic Chemistry
Inorganic Chemistry
5 years ago

Exploring the Hydrolytic Behavior of the Platinum(IV) Complexes with Axial Acetato Ligands

Exploring the Hydrolytic Behavior of the Platinum(IV) Complexes with Axial Acetato Ligands
Jian Zhao, Zichen Xu, Shaohua Gou, Jing Lin
Platinum(IV) complexes with axial acetato ligands can undergo hydrolysis under biologically revelant conditions, resulting in the loss of the equatorial chloride ligands. Further study indicated that increasing σ-donor ability of the amine group can promote the hydrolysis rate of the corresponding platinum(IV) complex.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01355

DOI: 10.1021/acs.inorgchem.7b01355

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