3 years ago

Boron “Doped” Polyacetylenes

Boron “Doped” Polyacetylenes
Zhen Zhang, Yang Qin, Keda Hu, James Burke
We report the synthesis and characterization of a novel series of main-chain boron-containing conjugated polymers (CPs), boron “doped” polyacetylenes (BPAs), which represent the first examples of main-chain boron-containing CPs without aromatic moieties within the polymer backbone, potentially enhancing electronic delocalization along the main-chain. These polymers are characterized by NMR, absorption and emission spectroscopy, cyclic voltammetry, theoretical calculation, and fluoride titration experiments, providing detailed understanding of the effects from different cross-conjugated side-chains on the physical and electronic properties of this new class of boron-containing polymers.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b05682

DOI: 10.1021/jacs.7b05682

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.