Crystal Growth & Design
Crystal Growth & Design
5 years ago

Directing the Distribution of Potassium Cations in Zeolite-LTL through Crown Ether Addition

Directing the Distribution of Potassium Cations in Zeolite-LTL through Crown Ether Addition
Minhyung Cho, Michael W. Anderson, Hae Sung Cho, Osamu Terasaki, Kyungmin Jeong, Keiichi Miyasaka, Jeung Ku Kang, Adam R. Hill
Zeolite LTL without crown ether shows large aspect ratio with small nucleation domains compared with the zeolite LTL including crown ether. Atomic coordinates analyzed by Rietveld refinement of X-ray diffraction data indicate that redistribution of potassium cation in the center of the pore cavity due to strong interaction between crown ether and potassium cation induced different crystal nucleation and growth behavior.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00832

DOI: 10.1021/acs.cgd.7b00832

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