Crystal Growth & Design
Crystal Growth & Design
5 years ago

Substituted Benzoxazole and Catechol Cocrystals as an Adsorbent for CO2 Capture: Synthesis and Mechanistic Studies

Substituted Benzoxazole and Catechol Cocrystals as an Adsorbent for CO2 Capture: Synthesis and Mechanistic Studies
Dharmalingam Sivanesan, Ki Tae Park, Hak Joo Kim, Soon Kwan Jeong, Min Hye Youn
The synthesis of cocrystals of a substituted benzoxazole and catechol from a primary amine and 3,5-di-tert-butylbenzoquinone is reported. By varying the equivalence of diketones, from 1 substituted benzoxazole and benzoxazoline were synthesized. Our results indicated the ability to use cocrystals for CO2 capture, and introduction of an amine into the cocrystal structure enhanced the CO2 adsorption capacity.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00693

DOI: 10.1021/acs.cgd.7b00693

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